On (not) deriving the entropy of barocaloric phase transitions from crystallography and neutron spectroscopy

We review well-known signatures of disorder in crystallographic and inelastic neutron scattering data. We show that these can arise from different types of disorder, corresponding to different values of the system entropy. Correlating the entropy of a material with its atomistic structure and dynamics is in general a difficult problem that requires correlating information between multiple experimental techniques including crystallography, spectroscopy, and calorimetry. These comments are illustrated with particular reference to barocalorics, but are relevant to a broad range of calorics and other disordered crystalline materials.Comment: 11 pages, 3 figure

MODISTools - downloading and processing MODIS remotely sensed data in R

Remotely sensed data – available at medium to high resolution across global spatial and temporal scales – are a valuable resource for ecologists. In particular, products from NASA's MODerate-resolution Imaging Spectroradiometer (MODIS), providing twice-daily global coverage, have been widely used for ecological applications. We present MODISTools, an R package designed to improve the accessing, downloading, and processing of remotely sensed MODIS data. MODISTools automates the process of data downloading and processing from any number of locations, time periods, and MODIS products. This automation reduces the risk of human error, and the researcher effort required compared to manual per-location downloads. The package will be particularly useful for ecological studies that include multiple sites, such as meta-analyses, observation networks, and globally distributed experiments. We give examples of the simple, reproducible workflow that MODISTools provides and of the checks that are carried out in the process. The end product is in a format that is amenable to statistical modeling. We analyzed the relationship between species richness across multiple higher taxa observed at 526 sites in temperate forests and vegetation indices, measures of aboveground net primary productivity. We downloaded MODIS derived vegetation index time series for each location where the species richness had been sampled, and summarized the data into three measures: maximum time-series value, temporal mean, and temporal variability. On average, species richness covaried positively with our vegetation index measures. Different higher taxa show different positive relationships with vegetation indices. Models had high R2 values, suggesting higher taxon identity and a gradient of vegetation index together explain most of the variation in species richness in our data. MODISTools can be used on Windows, Mac, and Linux platforms, and is available from CRAN and GitHub (https://github.com/seantuck12/MODISTools)

Internal waves and mixing near the Kerguelen Plateau

Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 46 (2016): 417-437, doi:10.1175/JPO-D-15-0055.1.In the stratified ocean, turbulent mixing is primarily attributed to the breaking of internal waves. As such, internal waves provide a link between large-scale forcing and small-scale mixing. The internal wave field north of the Kerguelen Plateau is characterized using 914 high-resolution hydrographic profiles from novel Electromagnetic Autonomous Profiling Explorer (EM-APEX) floats. Altogether, 46 coherent features are identified in the EM-APEX velocity profiles and interpreted in terms of internal wave kinematics. The large number of internal waves analyzed provides a quantitative framework for characterizing spatial variations in the internal wave field and for resolving generation versus propagation dynamics. Internal waves observed near the Kerguelen Plateau have a mean vertical wavelength of 200 m, a mean horizontal wavelength of 15 km, a mean period of 16 h, and a mean horizontal group velocity of 3 cm s−1. The internal wave characteristics are dependent on regional dynamics, suggesting that different generation mechanisms of internal waves dominate in different dynamical zones. The wave fields in the Subantarctic/Subtropical Front and the Polar Front Zone are influenced by the local small-scale topography and flow strength. The eddy-wave field is influenced by the large-scale flow structure, while the internal wave field in the Subantarctic Zone is controlled by atmospheric forcing. More importantly, the local generation of internal waves not only drives large-scale dissipation in the frontal region but also downstream from the plateau. Some internal waves in the frontal region are advected away from the plateau, contributing to mixing and stratification budgets elsewhere.A.M. was supported by the joint CSIRO-University of Tasmania Quantitative Marine Science (QMS) program and the 2009 CSIRO Wealth from Ocean Flagship Collaborative Fund. K.L.P.’s salary support was provided by Woods Hole Oceanographic Institution bridge support funds. B.M.S. was supported by the Australian Climate Change Science Program.2016-06-0

Turbulent mixing variability in an energetic standing meander of the Southern Ocean

Author Posting. © American Meteorological Society, 2022. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 52(8), (2022): 1593-1611, https://doi.org/10.1175/jpo-d-21-0180.1.This study presents novel observational estimates of turbulent dissipation and mixing in a standing meander between the Southeast Indian Ridge and the Macquarie Ridge in the Southern Ocean. By applying a finescale parameterization on the temperature, salinity, and velocity profiles collected from Electromagnetic Autonomous Profiling Explorer (EM-APEX) floats in the upper 1600 m, we estimated the intensity and spatial distribution of dissipation rate and diapycnal mixing along the float tracks and investigated the sources. The indirect estimates indicate strong spatial and temporal variability of turbulent mixing varying from O(10−6) to O(10−3) m2 s−1 in the upper 1600 m. Elevated turbulent mixing is mostly associated with the Subantarctic Front (SAF) and mesoscale eddies. In the upper 500 m, enhanced mixing is associated with downward-propagating wind-generated near-inertial waves as well as the interaction between cyclonic eddies and upward-propagating internal waves. In the study region, the local topography does not play a role in turbulent mixing in the upper part of the water column, which has similar values in profiles over rough and smooth topography. However, both remotely generated internal tides and lee waves could contribute to the upward-propagating energy. Our results point strongly to the generation of turbulent mixing through the interaction of internal waves and the intense mesoscale eddy field.The observations were funded through grants from the Australian Research Council Discovery Project (DP170102162) and Australia’s Marine National Facility. Surface drifters were provided by Dr. Shaun Dolk of the Global Drifter Program. AC was supported by an Australian Research Council Postdoctoral Fellowship. AC, HEP, and NLB acknowledge support from the Australian Government Department of the Environment and Energy National Environmental Science Program and the ARC Centre of Excellence in Climate Extremes. KP acknowledges the support from the National Science Foundation

Interannual variability of the South Indian Countercurrent

Author Posting. © American Geophysical Union, 2016. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Journal of Geophysical Research: Oceans 121 (2016): 3465–3487, doi:10.1002/2015JC011417.In the present work, we investigate the interannual variability of the South Indian Countercurrent (SICC), a major and still understudied current of the Indian Ocean circulation. To characterize the interannual variability of the SICC, four different data sets (altimetry, GLORYS, OFAM3, and SODA) are analyzed using multiple tools, which include Singular Spectrum Analysis and wavelet methods. The quasi-biennial band dominates the SICC low-frequency variance, with the main peak in the 1.5–1.8 year interval. A secondary peak (2.1–2.5 year) is only found in the western basin. Interannual and decadal-type modulations of the quasi-biennial signal are also identified. In addition, limitations of SODA before the 1960s in the SICC region are revealed. Within the quasi-biennial band, the SICC system presents two main patterns with a multiple jet structure. One pattern is characterized by a robust northern jet, while in the other the central jet is well developed and northern jet is weaker. In both patterns, the southern jet has always a strong signature. When the northern SICC jet is stronger, the northern cell of the subtropical gyre has a triangular shape, with its southern limb having a strong equatorward slant. The quasi-biennial variability of the SICC is probably related to the Indian Ocean tropical climate modes that are known to have a strong biennial characteristic.ARC Discovery Project Grant Number: DP130102088; NSF Grant Number: OCE-091716; Ocean Science Division of VM Oceanica2016-11-2

Near-surface salinity reveals the oceanic sources of moisture for Australian precipitation through atmospheric moisture transport

Author Posting. © American Meteorological Society, 2020. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 33(15), (2020): 6707-6730, https://doi.org/10.1175/JCLI-D-19-0579.1.The long-term trend of sea surface salinity (SSS) reveals an intensification of the global hydrological cycle due to human-induced climate change. This study demonstrates that SSS variability can also be used as a measure of terrestrial precipitation on interseasonal to interannual time scales, and to locate the source of moisture. Seasonal composites during El Niño–Southern Oscillation/Indian Ocean dipole (ENSO/IOD) events are used to understand the variations of moisture transport and precipitation over Australia, and their association with SSS variability. As ENSO/IOD events evolve, patterns of positive or negative SSS anomaly emerge in the Indo-Pacific warm pool region and are accompanied by atmospheric moisture transport anomalies toward Australia. During co-occurring La Niña and negative IOD events, salty anomalies around the Maritime Continent (north of Australia) indicate freshwater export and are associated with a significant moisture transport that converges over Australia to create anomalous wet conditions. In contrast, during co-occurring El Niño and positive IOD events, a moisture transport divergence anomaly over Australia results in anomalous dry conditions. The relationship between SSS and atmospheric moisture transport also holds for pure ENSO/IOD events but varies in magnitude and spatial pattern. The significant pattern correlation between the moisture flux divergence and SSS anomaly during the ENSO/IOD events highlights the associated ocean–atmosphere coupling. A case study of the extreme hydroclimatic events of Australia (e.g., the 2010/11 Brisbane flood) demonstrates that the changes in SSS occur before the peak of ENSO/IOD events. This raises the prospect that tracking of SSS variability could aid the prediction of Australian rainfall.This research is funded through the Earth System and Climate Change Hub of the Australian government’s National Environmental Science Programme. The assistance of computing resources from the National Computational Infrastructure supported by the Australian Government is acknowledged. CCU acknowledges support from the U.S. National Science Foundation under Grant OCE-1663704. MF was supported by the by Centre for Southern Hemisphere Oceans Research (CSHOR), which is a joint initiative between the Qingdao National Laboratory for Marine Science and Technology (QNLM), CSIRO, University of New South Wales and University of Tasmania. The authors wish to acknowledge PyFerret (https://ferret.pmel.noaa.gov/Ferret/) and the Cimate Data Operators (https://code.mpimet.mpg.de/projects/cdo/) for the data analysis and graphical representations in this paper

Mixing variability in the Southern Ocean

Author Posting. © American Meteorological Society, 2015. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Physical Oceanography 45 (2015): 966–987, doi:10.1175/JPO-D-14-0110.1.A key remaining challenge in oceanography is the understanding and parameterization of small-scale mixing. Evidence suggests that topographic features play a significant role in enhancing mixing in the Southern Ocean. This study uses 914 high-resolution hydrographic profiles from novel EM-APEX profiling floats to investigate turbulent mixing north of the Kerguelen Plateau, a major topographic feature in the Southern Ocean. A shear–strain finescale parameterization is applied to estimate diapycnal diffusivity in the upper 1600 m of the ocean. The indirect estimates of mixing match direct microstructure profiler observations made simultaneously. It is found that mixing intensities have strong spatial and temporal variability, ranging from O(10−6) to O(10−3) m2 s−1. This study identifies topographic roughness, current speed, and wind speed as the main factors controlling mixing intensity. Additionally, the authors find strong regional variability in mixing dynamics and enhanced mixing in the Antarctic Circumpolar Current frontal region. This enhanced mixing is attributed to dissipating internal waves generated by the interaction of the Antarctic Circumpolar Current and the topography of the Kerguelen Plateau. Extending the mixing observations from the Kerguelen region to the entire Southern Ocean, this study infers a large water mass transformation rate of 17 Sverdrups (Sv; 1 Sv ≡ 106 m3 s−1) across the boundary of Antarctic Intermediate Water and Upper Circumpolar Deep Water in the Antarctic Circumpolar Current. This work suggests that the contribution of mixing to the Southern Ocean overturning circulation budget is particularly significant in fronts.AM was supported by the joint CSIRO–University of Tasmania Quantitative Marine Science (QMS) program and the 2009 CSIRO Wealth from Ocean Flagship Collaborative Fund. BMS was supported by the Australian Climate Change Science Program, jointly funded by the Department of the Environment and CSIRO. KLPs salary support was provided by Woods Hole Oceanographic Institution bridge support funds.2015-10-0

Effectiveness and cost-effectiveness of a universal parenting skills programme in deprived communities : multicentre randomised controlled trial

Objective: To evaluate the effectiveness and cost utility of a universally provided early years parenting programme. Design: Multicentre randomised controlled trial with cost-effectiveness analysis. Setting: Early years centres in four deprived areas of South Wales. Participants: Families with children aged between 2 and 4 years. 286 families were recruited and randomly allocated to the intervention or waiting list control. Intervention: The Family Links Nurturing Programme (FLNP), a 10-week course with weekly 2 h facilitated group sessions. Main outcome measures: Negative and supportive parenting, child and parental well-being and costs assessed before the intervention, following the course (3 months) and at 9 months using standardised measures. Results: There were no significant differences in primary or secondary outcomes between trial arms at 3 or 9 months. With ‘+’ indicating improvement, difference in change in negative parenting score at 9 months was +0.90 (95%CI −1.90 to 3.69); in supportive parenting, +0.17 (95%CI −0.61 to 0.94); and 12 of the 17 secondary outcomes showed a non-significant positive effect in the FLNP arm. Based on changes in parental well-being (SF-12), the cost per quality-adjusted life year (QALY) gained was estimated to be £34 913 (range 21 485–46 578) over 5 years and £18 954 (range 11 664–25 287) over 10 years. Probability of cost per QALY gained below £30 000 was 47% at 5 years and 57% at 10 years. Attendance was low: 34% of intervention families attended no sessions (n=48); only 47% completed the course (n=68). Also, 19% of control families attended a parenting programme before 9-month follow-up. Conclusions: Our trial has not found evidence of clinical or cost utility for the FLNP in a universal setting. However, low levels of exposure and contamination mean that uncertainty remains. Trial registration: The trial is registered with Current Controlled Trials ISRCTN13919732

Dynamics in the ordered and disordered phases of barocaloric adamantane

High-entropy order-disorder phase transitions can be used for efficient and eco-friendly barocaloric solid-state cooling. Here the barocaloric effect is reported in an archetypal plastic crystal, adamantane. Adamantane has a colossal isothermally reversible entropy change of 106 J K-1 kg-1 . Extremely low hysteresis means that this can be accessed at pressure differences less than 200 bar. Configurational entropy can only account for about 40% of the total entropy change; the remainder is due to vibrational effects. Using neutron spectroscopy and supercell lattice dynamics calculations, it is found that this vibrational entropy change is mainly caused by softening in the high-entropy phase of acoustic modes that correspond to molecular rotations. We attribute this behaviour to the contrast between an 'interlocked' state in the low-entropy phase and sphere-like behaviour in the high-entropy phase. Although adamantane is a simple van der Waals solid with near-spherical molecules, this approach can be leveraged for the design of more complex barocaloric molecular crystals. Moreover, this study shows that supercell lattice dynamics calculations can accurately map the effect of orientational disorder on the phonon spectrum, paving the way for studying the vibrational entropy, thermal conductivity, and other thermodynamic effects in more complex materials.Comment: 14 pages, 6 figure